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The first 500 miles are the most important for break-in. You could change to synthetic oil at 500 miles and still have your engine break-in.
My rule is to go 500 miles, change the oil with petroleum again and then switch to synthetic at 1500 to 3000 miles. I've seen UOAs where engines that had 10,000 miles, and running synthetic oil still showed signs of "wear-in" metals.
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2004 Deepwater Nissan Titan, Crew Cab(10/24/04)
AMSOIL SVG 75w-140 gear lube
AMSOIL SAE 10w-30 oil
"No arsenal, or no weapon in the arsenals of the world, is so formidable as the will and moral courage of free men and women.
- Ronald Reagan
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