Longtubes are that simple, but shorties are not. The primary cats are welded to the OEM manifolds. Now, you can have the OEM cat welded to the new header (not recommended), but that could get pricey because they have to be put in, then the cats test fitted and tsck welded, then taken back off and welded, then re-installed.
If you just want to get this done and don't care about getting all the performance: Get high flow cats welded to the new headers and installed (same process as above)
If you want to get it done and have utilized the headers to get all the performance gains: Install a straight piece of 2" or 2.25" pipe from the new header to the PEM b-pipes, in place of the cats. Then swap out the OEM secondary cats in the b-pipes with High flow cats and move the 02 sensor behind them
Or, another option I just thought of. Add the high flow cats to the new Header and buy the walker direct fit b-pipes to eliminate your unnecassary secondary cats in the OEM b-pipes and leave the 02 sensor alone